Hirshfeld surface analysis and crystal structure of 7-methoxy-5-methyl-2-phenyl-11,12-dihydro-5,11-methano-1,2,4-triazolo[1,5-c][1,3,5]benzoxadiazocine
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CitationGumus, M. K., Kansiz, S., Dege, N., & Kalibabchuk, V. A. (2018). Hirshfeld surface analysis and crystal structure of 7-methoxy-5-methyl-2-phenyl-11, 12-dihydro-5, 11-methano-1, 2, 4-triazolo [1, 5-c][1, 3, 5] benzoxadiazocine. Acta Crystallographica Section E: Crystallographic Communications, 74(9), 1211-1214.
The title compound, C19H18N4O2, crystallizes with two independent moleculesin the asymmetric unit. The triazole ring is inclined to the benzene rings by9.63 (13) and 87.37 (12) in one molecule, and by 4.46 (13) and 86.15 (11) in theother. In the crystal, classical N—H N hydrogen bonds, weak C—H Ohydrogen bonds and weak C—H interactions link the molecules into athree-dimensional supramolecular network. Hirshfeld surface analysis and two-dimensional fingerprint plots were used to investigate the intermolecularinteractions present in the crystal, indicating that the most importantcontributions for the crystal packing are from H H (51.4%), H C/C H(26.7%), H O/O H (8.9%) and H N/N H (8%) interactions.