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dc.contributor.authorKamiloğlu, Ayşe Aktaş
dc.contributor.authorKaraca, Hüseyin
dc.contributor.authorÇelik, Gonca
dc.contributor.authorAcar, İrfan
dc.contributor.authorKantekin, Halit
dc.date.accessioned2020-02-17T07:19:15Z
dc.date.available2020-02-17T07:19:15Z
dc.date.issued2020en_US
dc.identifier.citationKamiloğlu, A. A., Karaca, H., Çelik, G., Acar, I., & Kantekin, H. (2020). New chalcone-substituted metallophthalocyanines: Synthesis, characterization, and investigation of their properties. Journal of Chemical Research, 44(7-8), 367-375, DOI: 10.1177/1747519820902684.en_US
dc.identifier.urihttps://hdl.handle.net/11494/1973
dc.descriptionThe author(s) disclosed receipt of the following financial support for the research, authorship, and/or publication of this article: This study was supported by the Research Fund of Artvin Çoruh University, Project no: 2018.F91.02.01 (Artvin-Turkey). Huseyin Karaca is grateful to the research fund of Sakarya University (BAPK: 2018-3-12-165).en_US
dc.description.abstractThe synthesis of novel metallophthalocyanines (M = Zn, Mg, and Co) derived from (E)-3-(3-bromophenyl)-1-(3-hydroxyphenyl)prop-2-en-1-one and (E)-3-(3-fluorophenyl)-1-(3-hydroxyphenyl)prop-2-en-1-one is achieved. These complexes and the synthesized novel phthalonitrile derivatives are characterized by FTIR, 1H NMR, 13C NMR, UV-Vis, mass spectrometry, and elemental analysis. The aggregation properties of the metallophthalocyanines ZnPc, MgPc, and CoPc are investigated in different solvents and at different concentrations in dimethyl formamide. The electrochemical behavior is also investigated. The cyclic voltammograms give one oxidation reaction for all the bromo-derived metallophthalocyanines and one reduction reaction for all the fluoro-derived metallophthalocyanines. Fe3+, Cd2+, Hg2+, Cu2+, Ni2+, and Co2+ ions are titrated fluorometrically with the phthalocyanines. The bromo- and fluoro-substituted phthalocyanine compounds show different effects on the metal ion titrations.en_US
dc.language.isoengen_US
dc.publisherSage Publicationsen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAggregationen_US
dc.subjectChalconesen_US
dc.subjectCyclic redoxen_US
dc.subjectMetal-sensingen_US
dc.subjectPhthalocyaninesen_US
dc.titleNew chalcone-substituted metallophthalocyanines: Synthesis, characterization, and investigation of their propertiesen_US
dc.typearticleen_US
dc.relation.journalJournal of Chemical Researchen_US
dc.departmentAÇÜ, Artvin Meslek Yüksekokuluen_US
dc.identifier.volume44
dc.identifier.issue7-8
dc.identifier.startpage367
dc.identifier.endpage375
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.identifier.doi10.1177/1747519820902684en_US
dc.contributor.institutionauthorKamiloğlu, Ayşe Aktaşen_US


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