Half-sandwich ruthenium(II) and iridium(III) complexes of imidazole based phosphinite ligands: antioxidant and antibacterial activities as well as electrochemical properties

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dc.contributor.authorIşık, Uğur
dc.contributor.authorRafikova, Khadichakhan
dc.contributor.authorMeriç, Nermin
dc.contributor.authorGüzel, Remziye
dc.contributor.authorKerimkulova, Aygül
dc.contributor.authorAkimbek, Arailym
dc.contributor.authorOkumuş, Veysi
dc.contributor.authorDurap, Feyyaz
dc.contributor.authorKayan, Cezmi
dc.contributor.authorAydemir, Murat
dc.date.accessioned2024-11-25T12:00:02Z
dc.date.available2024-11-25T12:00:02Z
dc.date.issued2024
dc.departmentAÇÜen_US
dc.description.abstractRuthenium(II) and iridium(III) complexes of phosphinites including imidazole moiety were synthesized and characterized by microanalysis, IR, MS, and NMR spectroscopies. Antibacterial activity against Gram-positive and Gram-negative bacterial strains was assessed in all complexes. The highest radical scavenging (72.2 %) was obtained for [3-(3-chloro-2-({[dichloro(?6-benzene)ruthenium]diphenylphosphanyl}oxy)propyl)-1-butyl-1H-imidazol-3-ium chloride], 4 at 200 ?g/mL concentration, while [3-(3-chloro-2-({[dichloro(??-pentamethylcyclopentadienyl)-iridium]diphenylphosphanyl}oxy)pro-pyl)-1-butyl-1H-imidazol-3-ium chloride], 6 demonstrated the highest antibacterial activity as 13 mm inhibition zone against E. hirea. Furthermore, optical and electrochemical featured of metal complexes containing imidazole phosphinite were investigated utilizing UV–vis absorption and cyclic voltammetry techniques. Consequently, all complexes can be proposed as metal-based charge convertible phosphinite complexes which may be employed as new generation and synergistic Dye-Sensitized Solar Cell (DSSC) materials.
dc.identifier.doi10.1002/slct.202304785
dc.identifier.issn2365-6549
dc.identifier.issue6en_US
dc.identifier.scopusqualityQ3
dc.identifier.urihttp://dx.doi.org/10.1002/slct.202304785
dc.identifier.urihttps://hdl.handle.net/11494/5008
dc.identifier.volume9en_US
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherJohn Wiley and Sons Incen_US
dc.relation.ispartofChemistrySelect
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/embargoedAccessen_US
dc.subjectAntibacterial/Biological Studyen_US
dc.subjectElectrochemical Propertiesen_US
dc.subjectImidazolium Salten_US
dc.subjectIonic Liquiden_US
dc.subjectPhosphinite Liganden_US
dc.subjectTransition Metalen_US
dc.titleHalf-sandwich ruthenium(II) and iridium(III) complexes of imidazole based phosphinite ligands: antioxidant and antibacterial activities as well as electrochemical propertiesen_US
dc.typeArticle

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