Synthesis and investigation of spectroelectrochemical properties of peripherally tetra-substituted phthalocyanine bearing 3-(4-{[3-(trifluoromethyl)benzyl]oxy}phenyl)propan-1-ol and its metallo compounds

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dc.contributor.authorKamiloğlu, Ayşe Aktaş
dc.contributor.authorAkyüz, Duygu
dc.contributor.authorKoca, Atık
dc.contributor.authorAcar, İrfan
dc.date.accessioned2020-02-06T12:18:35Z
dc.date.available2020-02-06T12:18:35Z
dc.date.issued2018
dc.departmentAÇÜ, Artvin Meslek Yüksekokuluen_US
dc.description.abstractIn this study, the new compounds; 3-(4-{[3-(trifluoromethyl)benzyl]oxy}phenyl)propan-1-ol 3 was prepared by the reaction of 4-(3-hydroxypropyl)phenol 1 with 1-(bromomethyl)-3-(trifluoromethyl)benzene 2 and 4-[3-(4-{[3 (trifluoromethyl)benzyl]oxy}phenyl)propoxy] phthalonitrile 5 was synthesized by the reaction of 4-nitrophthalonitrile 4 with 3-(4-{[3-(trifluoromethyl)benzyl]oxy}phenyl)propan-1-ol 3. Novel peripherally tetra substituted H2Pc 6, Co(II) 7, Cu(II) 8, Ni(II) 9 and Fe(II) 10 phthalocyanines, which have peripheral positions with 4-[3-(4-{[3 (trifluoromethyl)benzyl]oxy}phenyl)propoxy] groups, were synthesized and all of the new compounds characterized by IR, H-1 NMR, C-13 NMR, UV-Vis, mass spectroscopies and elemental analysis. The electrochemical and spectroelectrochemical investigation of the phthalocyanines carrying 4-[3-(4-{[3 (trifluoromethyl)benzyl]oxy}phenyl)propoxy] groups were studied using various electrochemical techniques in DMF on a glassy carbon electrode. Cyclic voltammetry and square wave voltammetry studies show that the complexes have either metal based or ligand-based diffusion controlled electron transfer properties. To shed more light on the electron-transfer steps of the complexes and assignments of the redox couples were carried out by spectroelectrochemical measurements. The color changes during spectral changes of redox species were recorded with in situ electrocolorimetric measurements. The electrochemical and in situ UV-Vis spectral change of complexes indicated their applicability in the fields of the electrochemical technologies.
dc.identifier.citationAktaş Kamiloğlu, A., Akyüz, D., Koca, A., & Acar, İ. (2018). Synthesis and investigation of spectroelectrochemical properties of peripherally tetra-substituted phthalocyanine bearing 3-(4-{[3-(trifluoromethyl)benzyl]oxy}phenyl)propan-1-ol and its metallo compounds. Journal of Inclusion Phenomena and Macrocyclic Chemistry: And Macrocyclic Chemistry, 92(1–2), 223. https://doi.org/10.1007/s10847-018-0837-6en_US
dc.identifier.doi10.1007/s10847-018-0837-6
dc.identifier.endpage235en_US
dc.identifier.issue1-2en_US
dc.identifier.scopusqualityQ2
dc.identifier.startpage223en_US
dc.identifier.urihttps://hdl.handle.net/11494/1949
dc.identifier.volume92en_US
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorKamiloğlu, Ayşe Aktaş
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofJournal of Inclusion Phenomena and Macrocyclic Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPhthalocyanineen_US
dc.subjectSynthesisen_US
dc.subjectElectrochemistryen_US
dc.subjectVoltammetryen_US
dc.titleSynthesis and investigation of spectroelectrochemical properties of peripherally tetra-substituted phthalocyanine bearing 3-(4-{[3-(trifluoromethyl)benzyl]oxy}phenyl)propan-1-ol and its metallo compoundsen_US
dc.typeArticle

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