Substituted Co(II) and Cu(II) metallophthalocyanines from new Schif base containing pyrrole units: Synthesis, characterization and investigation of photocatalytic activity on 2,3‑dichlorophenol oxidation
Yükleniyor...
Dosyalar
Tarih
2020
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Springer
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
In this article, novel Schif base compound 1 bearing pyrrole moiety has been synthesized from the reaction of 1-hydroxybenzaldehyde with 1,2-aminophenylpyrrole for the frst time. The cobalt phthalocyanine and copper phthalocyanine (3–4) were prepared by the cyclotetramerization of the novel phthalonitrile compound 2 and the corresponding metal salts. The new phthalonitrile compound 2 was synthesized by the reaction between 4-((E)-{[2-(1H-pyrro-1-yl)phenyl]imino}methyl) phenol 1 and 4-nitrophthalonitrile in DMF. The all new compounds (1–4) have been characterized by FT-IR spectroscopy, 1 H-NMR/13C-NMR, mass, UV–Vis spectroscopy techniques and elemental analysis (for metallophthalocyanines). Chlorinebearing phenols are of a class of pollutants. They have been regarded as a potential risk to environment and human health. It is important to advanced efective techniques to remove chlorinated phenols in wastewater. For this purpose, we investigated that diferent parameters infuenced the photooxidation process were determined and 2,3-dichlorophenol oxidize to the less harmfull products with high conversion and yield in the presence of Cu(II) and Co(II) phthalocyanine catalysts.
Açıklama
Anahtar Kelimeler
Metallophthalocyanine, Schiff Base, Pyrrole · 2,3, Dichlorophenol, Photocatalysis
Kaynak
Journal of Inclusion Phenomena and Macrocyclic Chemistry
WoS Q Değeri
N/A
Scopus Q Değeri
Q2
Cilt
96
Sayı
1-2
Künye
Aktaş Kamiloğlu, A., Saka, E. T., & Acar, I. (2020). Substituted Co(II) and Cu(II) metallophthalocyanines from new Schiff base containing pyrrole units: Synthesis, characterization and investigation of photocatalytic activity on 2,3-dichlorophenol oxidation. Journal of Inclusion Phenomena and Macrocyclic Chemistry, 96(1-2), 55-65, https://doi.org/10.1007/s10847-019-00949-z
