Synthesis, characterization, and photocatalytic activity of Co(II) and Cu(II) phthalocyanines linked with thiophene-Schiff base substituents for 4-nitrophenol oxidation

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dc.contributor.authorKamiloğlu, Ayşe Aktaş
dc.contributor.authorSaka, Ece Tuğba
dc.contributor.authorAcar, İrfan
dc.contributor.authorTekintaş, Kader
dc.date.accessioned2020-07-10T08:48:13Z
dc.date.available2020-07-10T08:48:13Z
dc.date.issued2019
dc.departmentAÇÜ, Artvin Meslek Yüksekokuluen_US
dc.description.abstractA phthalonitrile derivative 4-{4-[(E)-(thiophen-2-ylmethylidene)amino]phenoxy}phthalonitrile (2) and its Co(II) and Cu(II) phthalocyanine derivatives (2a, 2b) are reported. The compounds have been characterized by spectroscopic techniques (IR, NMR, UV-Vis, and MS) and elemental analyses (for the metallophthalocyanines). Photocatalytic activities of 2a and 2b on 4-nitrophenol (4-NP) oxidation are reported. Parameters influencing the photooxidation process were determined; 4-NP oxidizes to less harmful products with high conversion and yield in the presence of Co(II) and Cu(II) phthalocyanine catalysts.
dc.identifier.citationAktas Kamiloglu, A., Saka, E. T., Acar, I., & Tekintas, K. (2019). Synthesis, characterization, and photocatalytic activity of Co (II) and Cu (II) phthalocyanines linked with thiophene–Schiff base substituents for 4-nitrophenol oxidation. Journal of Coordination Chemistry, 72(16), 2778-2790. doi: 10.1080/00958972.2019.1657101.en_US
dc.identifier.doi10.1080/00958972.2019.1657101
dc.identifier.endpage2790en_US
dc.identifier.issue16en_US
dc.identifier.scopusqualityQ3
dc.identifier.startpage2778en_US
dc.identifier.urihttps://hdl.handle.net/11494/2142
dc.identifier.volume72en_US
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorKamiloğlu, Ayşe Aktaş
dc.language.isoenen_US
dc.publisherTaylor & Francis Incen_US
dc.relation.ispartofJournal of Coordination Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectMetallophthalocyanineen_US
dc.subjectThio-pheneen_US
dc.subject4-nitrophenolen_US
dc.subjectPhotocatalysisen_US
dc.subjectOxidationen_US
dc.titleSynthesis, characterization, and photocatalytic activity of Co(II) and Cu(II) phthalocyanines linked with thiophene-Schiff base substituents for 4-nitrophenol oxidationen_US
dc.typeArticle

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