Synthesis, structural characterization, and supramolecular assembly of a one-dimensional cobalt(II) coordination polymer with succinato and isonicotinamide ligands

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dc.contributor.authorKansız S.
dc.contributor.authorKaştaş G.
dc.contributor.authorDege N.
dc.contributor.authorAydın R.
dc.contributor.authorGümüş, Mustafa Kemal
dc.date.accessioned2025-06-20T11:12:10Z
dc.date.available2025-06-20T11:12:10Z
dc.date.issued2025
dc.departmentAÇÜ, Artvin Meslek Yüksekokulu, Laboratuvar Teknolojisi Bölümü
dc.description.abstractAbstract: A novel one-dimensional coordination polymer, catena-poly[μ-succinatobis(isonicotinamide-κN)diaquaco-balt(II)], [Co(suc)(ina)₂(H₂O)₂]n (suc = succinate, ina = isonicotinamide), was synthesized via the reaction of cobalt(II) chloride hexahydrate, sodium hydroxide, succinic acid, and isonicotinamide in aqueous methanol. Structural characterization using single crystal X-ray diffraction, FTIR spectroscopy, and thermal analysis revealed that Co(II) exhibits an octahedral coordination geometry, with succinate bridging the cobalt centers to form a one-dimensional polymeric chain. Extensive hydrogen bonding stabilizes the three-dimensional supramolecular architecture.
dc.identifier.doi10.1134/S0022476625040080
dc.identifier.endpage732
dc.identifier.issn00224766
dc.identifier.issue4
dc.identifier.scopus2-s2.0-105004464068
dc.identifier.scopusqualityQ4
dc.identifier.startpage722
dc.identifier.urihttps://hdl.handle.net/11494/5565
dc.identifier.volume66
dc.indekslendigikaynakScopus
dc.institutionauthorGümüş, Mustafa Kemal
dc.language.isoen
dc.publisherPleiades Publishing
dc.relation.ispartofJournal of Structural Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/embargoedAccess
dc.subjectCobalt(II)
dc.subjectCrystal structure
dc.subjectIsonicotinamide
dc.subjectPolymer
dc.subjectSuccinic acid
dc.subjectXRD
dc.titleSynthesis, structural characterization, and supramolecular assembly of a one-dimensional cobalt(II) coordination polymer with succinato and isonicotinamide ligands
dc.typeArticle

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