Synthesis, spectroscopic, and photophysicochemical behavior of Zn(II) and Mg(II) phthalocyanine– chalcone conjugates
Yükleniyor...
Tarih
2021
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Taylor and Francis Ltd.
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Phthalonitrile derivatives (8, 9, and 10) bearing different chalcone groups and their zinc(II) (ZnPcs) (8a, 9a, and 10a) and magnesium(II) (MgPcs) (8b, 9b, and 10b) complexes were prepared. The new compounds (5, 8–10, 8a–10a, and 8b–10b) were characterized by a combination of spectroscopic techniques, such as FT-IR, 1H NMR, 13C NMR (for 5, 8, 9, and 10), UV–Vis (for metallophthalocyanines), and MALDI-TOF mass spectra, and by elemental analysis (5, 8, 9, and 10). The aggregation behavior and photophysical (fluorescence quantum yields and lifetimes) and photochemical (singlet oxygen and photodegradation quantum yields) properties of different chalcone-substituted peripheral ZnPcs (8a, 9a, and 10a) and MgPcs (8b, 9b, and 10b) were investigated in dimethylsulfoxide (DMSO) to determine whether they are photosensitizers for photodynamic therapy (PDT) applications. The peripheral tetra-substituted MgPc (9b) showed longer lifetime than other compounds and unsubstituted ZnPc. The tetra-substituted ZnPc (9b) produced higher fluorescence quantum yield than the unsubstituted ZnPc and its chalcone-substituted counterparts. The ZnPcs (8a, 9a, and 10a) and MgPcs (8b, 9b, and 10b) showed low singlet oxygen production, but they showed quite high photostability, except MgPc 10b.
Açıklama
Anahtar Kelimeler
Chalcone, Fluorescence, Photophysicochemical properties, Phthalocyanine, Singlet oxygen
Kaynak
Journal of Coordination Chemistry
WoS Q Değeri
Q3
Scopus Q Değeri
Q3
Cilt
Article in pres
Sayı
Künye
Aktas Kamiloğlu, A., Yalazan, H., Durmuş, M., Çelik, G., Ömeroğlu, I., Acar, I., & Kantekin, H. (2021). Synthesis, spectroscopic, and photophysicochemical behavior of Zn (II) and Mg (II) phthalocyanine–chalcone conjugates. Journal of Coordination Chemistry, 1-17.
