Photophysical, photochemical properties of chalcone substituted Zinc(II) and Magnesium(II) metallophthalocyanines bearing thiophene units
Yükleniyor...
Dosyalar
Tarih
2022
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Springer
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
The novel thiophene-chalcone compound (2), phthalonitrile derivatives bearing thiophene-chalcone group (3 and 4) and their zinc (II) (ZnPcs) (3a and 4a) and magnesium (II) (MgPcs) (3b and 4b) phthalocyanine compounds were synthesized in this study. The structure of all these new compounds were elucidated by spectroscopic techniques like IR, 1 H NMR, 13 C NMR (for compounds 2, 3 and 4), MALDI–TOF mass and UV-Vis. The fuorescence quantum yields and lifetimes (photophysical properties), and the singlet oxygen and photodegradation quantum yields (photochemical properties) of thiophene bearing chalcone substituted ZnPcs (3a and 4a) and MgPcs (3b and 4b) were studied in DMSO (dimethylsulfoxide) to determine if they are convenient photosensitizers for photodynamic therapy (PDT) applications.
Açıklama
Anahtar Kelimeler
Phthalocyanine, Thiophene, Photophysicochemical, Fluorescence, Singlet oxygen
Kaynak
Journal Of Inclusion Phenomena And Macrocyclic Chemistry
WoS Q Değeri
Q3
Scopus Q Değeri
Q2
Cilt
102
Sayı
7-8
Künye
Aktas Kamiloglu, A., Omeroglu, I., Yalazan, H., Durmus, M., Celik, G., & Kantekin, H. (2022). Photophysical, photochemical properties of chalcone substituted Zinc (II) and Magnesium (II) metallophthalocyanines bearing thiophene units. Journal of Inclusion Phenomena and Macrocyclic Chemistry, 102(7-8), 693-703.
