O-Acetylation: synthesis of acetylated phenols from aryl-methyl ethers over boron alkoxides

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dc.contributor.authorBalaydın, Halis Türker
dc.date.accessioned2021-12-10T11:40:02Z
dc.date.available2021-12-10T11:40:02Z
dc.date.issued2012
dc.departmentAÇÜ, Eğitim Fakültesi, Temel Eğitim Bölümüen_US
dc.description.abstractA new acetylation procedure has been applied to 13 aryl-methyl ethers using boron chemistry. In this procedure, demethylation of aryl-methyl ethers and acetylation of the resulting phenols were combined into one procedure in order to shorten the number of stages and to achieve easy purification. Eleven known with/without bromine and two new [bis(3,4-diacetoxyphenyl)methanone and 5,5'-methylenebis(1,2-diacetoxy-3,4-dibromobenzene) (a natural bromophenol's acetylated derivative)] acetylated arene compounds were synthesised from their methoxy derivatives by this method. The effectiveness of the method was illustrated by producing an acetylated natural bromophenol from its methyl ether. The phenol form was obtained by hydrolysing the acetylated natural bromophenol. Thus, the advantage of this method in the natural product chemistry of phenolic compounds was confirmed.
dc.identifier.citationBalaydın, H. T. (2012). O-Acetylation: synthesis of acetylated phenols from aryl-methyl ethers over boron alkoxides. Journal of Chemical Research, 36(4), 238-240.en_US
dc.identifier.doi10.3184/174751912X13324176277811
dc.identifier.endpage240en_US
dc.identifier.issue4en_US
dc.identifier.scopusqualityQ3
dc.identifier.startpage238en_US
dc.identifier.urihttps://hdl.handle.net/11494/3601
dc.identifier.volume36en_US
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorBalaydın, Halis Türker
dc.language.isoenen_US
dc.publisherSage Publicationsen_US
dc.relation.ispartofJournal of Chemical Research
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectNatural bromophenolsen_US
dc.subjectAcetylationen_US
dc.subjectAryl etheren_US
dc.subjectBoron chemistryen_US
dc.titleO-Acetylation: synthesis of acetylated phenols from aryl-methyl ethers over boron alkoxidesen_US
dc.typeArticle

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