New chalcone-substituted metallophthalocyanines: Synthesis, characterization, and investigation of their properties
Yükleniyor...
Dosyalar
Tarih
2020
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Sage Publications
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
The synthesis of novel metallophthalocyanines (M = Zn, Mg, and Co) derived from (E)-3-(3-bromophenyl)-1-(3-hydroxyphenyl)prop-2-en-1-one and (E)-3-(3-fluorophenyl)-1-(3-hydroxyphenyl)prop-2-en-1-one is achieved. These complexes and the synthesized novel phthalonitrile derivatives are characterized by FTIR, 1H NMR, 13C NMR, UV-Vis, mass spectrometry, and elemental analysis. The aggregation properties of the metallophthalocyanines ZnPc, MgPc, and CoPc are investigated in different solvents and at different concentrations in dimethyl formamide. The electrochemical behavior is also investigated. The cyclic voltammograms give one oxidation reaction for all the bromo-derived metallophthalocyanines and one reduction reaction for all the fluoro-derived metallophthalocyanines. Fe3+, Cd2+, Hg2+, Cu2+, Ni2+, and Co2+ ions are titrated fluorometrically with the phthalocyanines. The bromo- and fluoro-substituted phthalocyanine compounds show different effects on the metal ion titrations.
Açıklama
The author(s) disclosed receipt of the following financial support for the research, authorship, and/or publication of this article: This study was supported by the Research Fund of Artvin Çoruh University, Project no: 2018.F91.02.01 (Artvin-Turkey). Huseyin Karaca is grateful to the research fund of Sakarya University (BAPK: 2018-3-12-165).
Anahtar Kelimeler
Aggregation, Chalcones, Cyclic redox, Metal-sensing, Phthalocyanines
Kaynak
Journal of Chemical Research
WoS Q Değeri
Q4
Scopus Q Değeri
Q3
Cilt
44
Sayı
7-8
Künye
Kamiloğlu, A. A., Karaca, H., Çelik, G., Acar, I., & Kantekin, H. (2020). New chalcone-substituted metallophthalocyanines: Synthesis, characterization, and investigation of their properties. Journal of Chemical Research, 44(7-8), 367-375, DOI: 10.1177/1747519820902684.
