Crystal structure and Hirshfeld surface analysis of 3-(hydroxymethyl)-3-methyl-2,6-diphenylpiperidin-4-one
Yükleniyor...
Tarih
2022
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
International Union of Crystallography
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
A new synthesis of the title compound, C19H21NO2, was developed with good yield and purity using the reaction of 4-hydroxy-3-methyl-2-butanone, benzaldehyde and ammonium acetate in glacial acetic acid as a solvent. The central piperidine ring adopts a chair conformation, and its least-squares basal plane forms dihedral angles of 85.71?(11) and 77.27?(11)° with the terminal aromatic rings. In the crystal, the molecules are linked by O-H?O and C-H?O hydrogen bonds into double ribbons. The Hirshfeld surface analysis shows that the most important contributions are from H?H (68%), C?H/H?C (19%) and O?H/H?O (12%) interactions.
Açıklama
Anahtar Kelimeler
4-hydroxy-3-methyl-2-butanone, Ammonium acetate, Benzaldehyde, Crystal structure, Hirshfeld surface, Hydrogen bonding, Piperidone
Kaynak
Acta Crystallographica Section E: Crystallographic Communications
WoS Q Değeri
N/A
Scopus Q Değeri
Q3
Cilt
78
Sayı
1
Künye
Gümüş, M. K., Kansiz, S., Tulemisova, G. B., Dege, N., & Saif, E. (2022). Crystal structure and Hirshfeld surface analysis of 3-(hydroxymethyl)-3-methyl-2, 6-diphenylpiperidin-4-one. Acta Crystallographica Section E: Crystallographic Communications, 78(1), 29-32, 1.
